I would use clear Swarovski crystals. I make jewelry with them. It's hard to suggest how to attach them without knowing what they look like. Fabric glue would work, but not that great. If they are a satin-y shoe, you could sew them on.
If you are looking to buy a lot of the crystals, I would go to www.firemountaingems.com and search for Swarovski. You'll find a much better deal in bulk there.
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